SCHEDULED MAINTENANCE
Photosensitized oxygenation of 1-ethylthio-cyclohexene gave a C–C bond cleavage product via an intermediate sulphur substituted dioxetan, but when 1-ethylthio-4-t-butylcyclohexene was used both C–C and C–S cleavage products were produced; the relative cleavage of the C–S and C–C bonds was affected by the conformation of the intermediate dioxetans.
W. Ando, K. Watanabe and T. Migita, J. Chem. Soc., Chem. Commun., 1975, 961 DOI: 10.1039/C39750000961
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