Aromatic hydroxylation mediated by flavin autoxidation: lack of the NIH shift
Abstract
Aromatic hydroxylations by two flavin mono-oxygenase model systems show low values of the NIH shift suggesting that these oxidations are free-radical processes.
Aromatic hydroxylations by two flavin mono-oxygenase model systems show low values of the NIH shift suggesting that these oxidations are free-radical processes.
J. R. L. Smith, D. M. Jerina, S. Kaufman and S. Milstein, J. Chem. Soc., Chem. Commun., 1975, 881 DOI: 10.1039/C39750000881
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