Issue 7, 1974
From the journal:

Journal of the Chemical Society, Dalton Transactions

Dithiocarbamato- and carbonyldithiocarbamato-complexes of rhenium-(I), -(III), -(IV), and -(V)

John F. Rowbottom  and  Geoffrey Wilkinson  

Abstract

Dithiocarbamato-complexes of rhenium such as Re(CO)(S2CNR2)3(R = Me, Et, PhCH2), ReCl2(S2CNR2)2(R = Et, PhCH2), and Re2O2S{S2CN(PhCH2)2}4, and complex ions such as [Re(S2CNEt2)4]+ and [Re(CO)3(S2CNEt2)X]–(X = Cl, I), have been prepared by interaction of Re(CO)5Cl and thiuram disulphides.

Interaction of Tl(S2CNEt2) and Re(CO)5Cl leads to [Re(CO)3(S2CNEt2)]2 which is easily cleaved by CO, pyridine, and PPh3 to Re(CO)3(S2CNEt2)(L).

The reaction of ReCl4(PPh3)2 with [Et2NCS2]2 leads to [Re2Cl2(Et2NCS2)5]Cl2 as well as ReCl2(S2CNEt2)2 and [Re(S2CNEt2)4]+.

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Article information

DOI
https://doi.org/10.1039/DT9740000684
Article type
Paper

J. Chem. Soc., Dalton Trans., 1974, 684-689

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Dithiocarbamato- and carbonyldithiocarbamato-complexes of rhenium-(I), -(III), -(IV), and -(V)

J. F. Rowbottom and G. Wilkinson, J. Chem. Soc., Dalton Trans., 1974, 684 DOI: 10.1039/DT9740000684

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