X-ray structure analysis has shown that the anion monothiothenoyltrifluoroacetonatopentacarbonyltungstate(O)(I) is the first metal complex in which a β-diketone type of ligand has been observed in its trans-isomeric form.
M. McPartlin, G. B. Robertson, G. H. Barnett and M. K. Cooper, J. Chem. Soc., Chem. Commun., 1974, 305 DOI: 10.1039/C39740000305
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