Issue 6, 1974

Thermal and photochemical decompositions of 5-exo- and 5-endo-methyl-2-cyano-3,4-diazapentacyclo[6,4,0,02,6,07,11,010,12]dodec-3-ene: a lowered stereoselectivity by the steric inhibitions of the rotation of an intermediate nitrogen-containing diradical

Abstract

Considerably lower stereoselective formation of the single inversion product was observed for 5-endo-methyl 2-cyano-3,4-diazapentacyclo[6,4,0,02,6,07,11,07,11,010,12]dodec-3-ene [endo-(3)] compared to its exo-isomer in their thermal and direct photodecompositions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 227-228

Thermal and photochemical decompositions of 5-exo- and 5-endo-methyl-2-cyano-3,4-diazapentacyclo[6,4,0,02,6,07,11,010,12]dodec-3-ene: a lowered stereoselectivity by the steric inhibitions of the rotation of an intermediate nitrogen-containing diradical

T. Sasaki, S. Eguchi and F. Hibi, J. Chem. Soc., Chem. Commun., 1974, 227 DOI: 10.1039/C39740000227

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