Treatment of alkoxides with (thiobenzoylthio)acetic acid gives thiobenzoic acid O-esters in high yield. Similarly, the reaction of alkoxides with 2,4-dinitrophenyl dithiobenzoate (IX) gives the corresponding thiobenzoic acid O-ester. Imidate salts react with hydrogen sulphide in pyridine to give thioacid O-esters in good yields.
D. H. R. Barton, C. Chavis, M. K. Kaloustian, P. D. Magnus, G. A. Poulton and P. J. West, J. Chem. Soc., Perkin Trans. 1, 1973, 1571 DOI: 10.1039/P19730001571
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