Only Ph3Al and Ph3Ga of the Group IIIB metal triphenyls produce ions derived from the dimers Ph6M2 under electron impact. Fragmentation behaviour reflects the progressive weakening of the Ph–M bond as the series is descended. Appearance potential measurements are reported for the major metal-containing ions and D(Ph2M+–Ph) evaluated.
F. Glockling and J. G. Irwin, J. Chem. Soc., Dalton Trans., 1973, 1424 DOI: 10.1039/DT9730001424
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