It was demonstrated that among a number of hexosamines tested as precursors of the mitomycin antibiotics, D-glucosamine was most efficiently incorporated, and that it can provide the nitrogen atom of the aziridine ring of mitomycin B.
U. Hornemann and M. J. Aikman, J. Chem. Soc., Chem. Commun., 1973, 88b DOI: 10.1039/C3973000088B
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