A relationship exists between conformational energy differences in 1,2-disubstituted ethanes and the polar nature of the substituents; a parallel may be drawn with the observed stereochemistry of addition to olefins.
L. Phillips and V. Wray, J. Chem. Soc., Chem. Commun., 1973, 90 DOI: 10.1039/C39730000090
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