4-Methylenebicyclo[3,2,0]hept-2-enes are shown to undergo photofragmentation reactions from the excited singlet state and, depending on the substitution pattern, may undergo rearrangement to norbornene derivatives from both singlet and triplet states.
N. K. Hamer and A. J. Wills, J. Chem. Soc., Chem. Commun., 1973, 458 DOI: 10.1039/C39730000458
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