Hexafluorobenzene undergoes a photoreaction with benzene to give 2,3,4,5,6-pentafluorobiphenyl: the process is unusual in that it can be sensitised by naphthalene, is susceptible to polarity effects, and may not involve free C6F5· radicals.
D. Bryce-Smith, A. Gilbert and P. J. Twitchett, J. Chem. Soc., Chem. Commun., 1973, 457 DOI: 10.1039/C39730000457
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