Issue 12, 1973

The nature of the α-sulphinyl carbanion derived from methyl 1-phenylethyl sulphoxide

Abstract

For hydroxide-ion-catalysed proton removal from methyl 1-phenylethyl sulphoxide kex/kep= 1·30 (ex refers to exchange and ep to epimerization), a result consistent with the intervention of either two rapidly inverting pyramidal anions or a single planar anion.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 398-399

The nature of the α-sulphinyl carbanion derived from methyl 1-phenylethyl sulphoxide

M. B. D'Amore and J. I. Brauman, J. Chem. Soc., Chem. Commun., 1973, 398 DOI: 10.1039/C39730000398

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