Conversion of NN′-dialkylsulphamides into azoalkanes. Formation of the thiadiaziridine 1,1-dioxide ring system
Abstract
NN′-Di-t-butylsulphamide is converted into trans-2,2′-dimethyl-2,2′-azopropane via the formation of an N-sulphamide anion and 2,3-dt-butylthiadiaziridine 1,1-dioxide.