Issue 10, 1973
From the journal:

Journal of the Chemical Society, Chemical Communications

Free-radical displacement reactions at a transition-metal centre: bimolecular homolytic substitution (SH2) at square-planar PtII

David J. Cardin,   Michael F. Lappert  and  Peter W. Lednor  

Abstract

The displacement of the free radical R· from the complex cis-PtR2X2(R = Me, Et, Me3SiCH2, or PhCH2; X = PAlk3 or PMe2Ph; Alk = Et, Prn, or Bun) by ButO· or PhS· is demonstrated by e.s.r. spectroscopy (direct detection or spin-trapping) or by initiation of a chain reaction involving R·.

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Article information

DOI
https://doi.org/10.1039/C39730000350
Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 350-350

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Free-radical displacement reactions at a transition-metal centre: bimolecular homolytic substitution (SH2) at square-planar PtII

D. J. Cardin, M. F. Lappert and P. W. Lednor, J. Chem. Soc., Chem. Commun., 1973, 350 DOI: 10.1039/C39730000350

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