SCHEDULED MAINTENANCE
Reaction of α-bromo-esters derived from allylic and acetylenic alcohols with zinc dust provides a useful synthesis of γδ-unsaturated acids, via[3,3]-sigmatropic rearrangement of the intermediate zinc enolate, the efficiency depending upon substitution and solvent.
J. E. Baldwin and J. A. Walker, J. Chem. Soc., Chem. Commun., 1973, 117 DOI: 10.1039/C39730000117
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