Reaction of the chloroallyl radical with molecular chlorine
Abstract
The relative reactivities of the two sites of the chloroallyl radical towards a chlorine molecule have been measured at 350–500 °C; the ratio of rate constants for the formation of 1,3- and 3,3-dichloropropene is given by: k1,3/k3,3= 100·73 ± 0·10 exp (+ 1130 ± 300/RT)