Trichloronitrosomethane decomposes within 3 hours at 100 °C to give nitrogen, nitric oxide, nitrosyl chloride, carbon tetrachloride, N-(dichloromethylene)trichloromethylamine N-oxide, and phosgene. The dichloronitrosomethyl radical is postulated as a reaction intermediate and a simple MO picture of bonding in that radical is outlined.
V. Astley and H. Sutcliffe, J. Chem. Soc., Perkin Trans. 2, 1972, 197 DOI: 10.1039/P29720000197
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