An amino-sugar, vancosamine, derived from the antibiotic vancomycin, is shown to be 3-amino-2,3,6-trideoxy-3-C-methyl-L-Iyxo-hexopyranose (1). A number of acylated derivatives have been prepared and their physical properties, particularly c.d. and n.m.r. spectra, have been compared and evaluated.
A. W. Johnson, R. M. Smith and R. D. Guthrie, J. Chem. Soc., Perkin Trans. 1, 1972, 2153 DOI: 10.1039/P19720002153
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