SCHEDULED MAINTENANCE
Vibronic structure observed in the circular dichroism of (+)[Co(en)3]3+ and α-Ni(H2O)6SO4 is analyzed in terms of the theory of Weigang. The rotational strength of the magnetic dipole allowed 1A1(1A1g)→1E(1T1g) transition of (+)[Co(en)3]3+ is predominantly static in origin, whereas that of the magnetic dipole forbidden 3A2g→3aT1g transition of α-Ni(H2O)6SO4 is predominantly vibronic in origin.
M. J. Harding, J. Chem. Soc., Faraday Trans. 2, 1972, 68, 234 DOI: 10.1039/F29726800234
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