Dithiocarbamate complexes of oxorhenium(V) such as ReOCl2(S2CNEt2)(PPh3), ReOCl(S2CNR2)2, and Re2O3-(S2CNR2)4 have been prepared from ReOCl3(PPh3)2.
The interaction of a variety of chloro-complexes of rhenium with dithiocarbamates leads to the compounds [Re(NPh)(S2CNEt2)2]2O, Re(NPh) Cl(S2CNEt2)2, ReN(S2CNEt2)3, and ReCl2(S2CNEt2)(PPh3)2. The properties and infrared spectra are reported.
J. F. Rowbottom and G. Wilkinson, J. Chem. Soc., Dalton Trans., 1972, 826 DOI: 10.1039/DT9720000826
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