In tetrabromotris(dimethylphenylphosphine)molybdenum(IV), the metal atom has a capped octahedral (C3v) environment with a bromine atom occupying the unique capping position.
M. G. B. Drew, J. D. Wilkins and A. P. Wolters, J. Chem. Soc., Chem. Commun., 1972, 1278 DOI: 10.1039/C39720001278
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