Four diastereomeric pairs of complexes of the type [Co(S-amino-acid)(acetylacetone)2] were separated by column chromatography on alumina, and the (+)D isomers were assigned the Λ absolute configuration by 1H n.m.r. spectroscopy.
D. J. Seematter and J. G. Brushmiller, J. Chem. Soc., Chem. Commun., 1972, 1277 DOI: 10.1039/C39720001277
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