Issue 22, 1972
From the journal:

Journal of the Chemical Society, Chemical Communications

Stereochemistry of cleavage of silicon–platinum bonds in optically active silicon–platinum compounds

C. Eaborn,   D. J. Tune  and  D. R. M. Walton  

Abstract

The cleavage of the Si–Pt bond in trans-(+)-[PtCl(*SiR3)(PPhMe2)2][R3Si*= MePh(1-naphthyl)Si] by LiAlH4, PhSH, or Et3SiH, and of that in (–)-[PtH(*SiR3)(PPh3)2] by LiAlH4, PhCOCl, PhC[triple bond, length half m-dash]CH, or PhSH occurs with predominant retention of configuration at silicon.

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Article information

DOI
https://doi.org/10.1039/C39720001223
Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 1223-1224

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Stereochemistry of cleavage of silicon–platinum bonds in optically active silicon–platinum compounds

C. Eaborn, D. J. Tune and D. R. M. Walton, J. Chem. Soc., Chem. Commun., 1972, 1223 DOI: 10.1039/C39720001223

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