Issue 21, 1972

Evidence for octa-co-ordination in alcohol–lanthanide-shift-reagent complexes and its implications in the search for the geometric factor govering observed shifts

Abstract

The c.d. spectral changes induced in the euroium 5F05D1 band (524 nm) of the shift reagent, Eu(fod)3, on complexing optically active alcohols indicate that the major species present at standard n.m.r. concentrations and ratios is octa-co-ordinated, Eu(fod)3(ROH)2.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 1193-1194

Evidence for octa-co-ordination in alcohol–lanthanide-shift-reagent complexes and its implications in the search for the geometric factor govering observed shifts

N. H. Andersen, B. J. Bottino and S. E. Smith, J. Chem. Soc., Chem. Commun., 1972, 1193 DOI: 10.1039/C39720001193

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