The C-2 protons of mevalonic acid are incorporated with retention of configuration into C-22 of fusidic acid; this finding excludes the intermediacy of products with a Δ20(22) double bond in the formation of a Δ17(20) double bond in fusidic acid.
E. Caspi, R. C. Ebersole, W. O. Godtfredsen and S. Vangedal, J. Chem. Soc., Chem. Commun., 1972, 1191 DOI: 10.1039/C39720001191
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