The reduction of chromate ion in the presence of perfluoropinacol (PFP) leads to the formation of stable, chelated, alkoxides containing chromium(V) in the ion [GrO(PFP)2]–, the cations being K+, Cs+ or Et4N+; the isoelectronic vanadium(IV) complex, [VO(PFP)2]22–, may be prepared by reaction of PFP with a vanadyl salt.
C. J. Willis, J. Chem. Soc., Chem. Commun., 1972, 944 DOI: 10.1039/C39720000944
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