α-Halogenomethyl sulphoxides react with PrnO– and EtS– in PrnOH via SN2 substitution; α0halogenoethyl and isopropyl derivatives react more slowly: SN2 reactions are greatly retarded by steric effects and SN1 reactions by the effect of the SO group.
M. Cinquini, D. Landini and A. Maia, J. Chem. Soc., Chem. Commun., 1972, 734 DOI: 10.1039/C39720000734
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