Alkylation of lithium dihydroanthracenylide by (–)R-6-chloro-2,6-dimethyloctane occurs with racemization and only a small degree of inversion of configuration, in agreement with the main pathway involving the previously proposed radical–radical anion combination.
J. Mazaleyrat and Z. Welvart, J. Chem. Soc., Chem. Commun., 1972, 546 DOI: 10.1039/C39720000546
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