The reaction of cis,trans- or trans,trans-hexa-2,4-diene and Ru3(CO)12 is shown, by 1H and 13C n.m.r. spectra and X-ray crystal structure to give a product in which the diene ligand has undergone a skeletal rearrangement producing a π-allyl group, a metal hydride bond, and two metal–carbon σ-bonds.
M. Evans, M. Hursthouse, E. W. Randall, E. Rosenberg, L. Milone and M. Valle, J. Chem. Soc., Chem. Commun., 1972, 545 DOI: 10.1039/C39720000545
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