Rate constants (in M–1S–1) for the primary initiation stage of borane autoxidations have been found to be 1·8 × 10–3 for tri-s-butylborane, 0·9 × 10–3 for tri-isobutylborane, and 21·9 × 10–3 for tricyclohexylborane at 25° in benzene; the reaction is first order in borane and oxygen.
P. B. Brindley and J. C. Hodgson, J. Chem. Soc., Chem. Commun., 1972, 202 DOI: 10.1039/C39720000202
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