Issue 3, 1972

Bredt's rule: an anomalous decarboxylation

Abstract

Since the thermal monodecarboxylation of (+)-bicyclo[2,2,2]octan-2,5-dione-1,4-dicarboxylic acid is found to proceed with racemisation, the mechanism cannot involve a bridgehead double bond and so does not infringe Bredt's Rule.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 201-202

Bredt's rule: an anomalous decarboxylation

G. L. Buchanan, N. B. Kean and R. Taylor, J. Chem. Soc., Chem. Commun., 1972, 201 DOI: 10.1039/C39720000201

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