Issue 2, 1972

A stereospecific exchange reaction at the β-CH2 of phenylalanine, competing with gliotoxin biosynthesis

Abstract

Gliotoxin biosynthesis in Trichoderma viride proceeds with the retention of both hydrogens of the CH2 group of phenylalanine, but in competition with a stereospecific reaction of the phenylalanine in which the 3′-S-hydrogen is exchanged.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 100-101

A stereospecific exchange reaction at the β-CH2 of phenylalanine, competing with gliotoxin biosynthesis

J. D. Bu'Lock, A. P. Ryles, N. Johns and G. W. Kirby, J. Chem. Soc., Chem. Commun., 1972, 100 DOI: 10.1039/C39720000100

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