Deamination of 7β-aminomethyl-6,14-endo-etheno-7-methyltetrahydrothebaine (1a) gives the C-homocodeinone derivative (7) whereas the corresponding ethano-derivative undergoes ring expansion only.
J. W. Lewis and M. J. Readhead, J. Chem. Soc. C, 1971, 2298 DOI: 10.1039/J39710002298
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