A variety of ketone oximes have been converted into NN-disubstituted thiocarbamate O-esters. Some of the latter undergo a novel, thermal thione–thiol rearrangement to give thio-oxime carbamates.
B. Cross, R. J. G. Searle and R. E. Woodall, J. Chem. Soc. C, 1971, 1833 DOI: 10.1039/J39710001833
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