Decafluorophenanthrene reacts with sodium methoxide and with dimethylamine with replacement of the fluorine atoms at positions 2 and 7. This has been proved by n.m.r. spectroscopy and by chemical means. Polyfluorophenanthrenes are oxidised to polyfluorobiphenyl-2,2′-dicarboxylic acids by potassium permanganate.
J. Burdon, B. L. Kane and J. C. Tatlow, J. Chem. Soc. C, 1971, 1601 DOI: 10.1039/J39710001601
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