By utilising the specific hydroxylating capabilities of the fungi Aspergillus ochraceus Wilhelm and Penicillium urticae Bain in combination with standard chemical reactions, 5α-androstan-15α-ol has been obtained from 3α-hydroxy-5α-androstan-17-one in an overall yield of 16%.
J. W. Blunt, I. M. Clark, J. M. Evans, E. R. H. Jones, G. D. Meakins and J. T. Pinhey, J. Chem. Soc. C, 1971, 1136 DOI: 10.1039/J39710001136
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