The properties and equilibration of the title compounds are described. The cis-trans equilibrium in 2,6-dimethyl-cyclohexanone itself is little affected by solvent. The results are discussed in terms of 1,3-diaxial steric interactions and are shown to support the low steric requirements of lone pairs when the probe is a methyl group.
M. D. Brown, M. J. Cook and A. R. Katritzky, J. Chem. Soc. B, 1971, 2358 DOI: 10.1039/J29710002358
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