SCHEDULED MAINTENANCE
The gas-phase equilibrium CH3·CO2H + CH2·CO ⇌(CH3·CO)2O has been studied over the temperature range 171–289°C, starting from both sides. The value of K is given by the equation log (K atm–1)= 4579/T– 6·738, ΔH°=–87·5 kJ mol–1, and ΔS°=–128·8 JK–1 mol–1. The results are compared with values calculated from the kinetic parameters of the forward and backward reactions.
P. G. Blake, H. H. Davies and A. Speis, J. Chem. Soc. B, 1971, 2050 DOI: 10.1039/J29710002050
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