Issue 0, 1971

Raman spectra of gaseous, liquid, and solid bismuth trichloride. Resonance fluorescence spectra of gaseous BiCl and BiBr

Abstract

Comparison of the gas-phase Raman spectrum of BiCl3 at 460 °C with that of the solid and the melt shows that strong interactions are operative in the solid and melt, probably chlorine bridges between molecules. Gas-phase Raman data could not be obtained for BiBr3 owing to intense resonance fluorescence from BiBr, a thermal dissociation product. Attempted gas phase Raman studies of BiCl3 above 700 °C resulted in a similar dissociation with analogous fluorescence attributed to BiCl.

Article information

Article type
Paper

J. Chem. Soc. A, 1971, 3157-3159

Raman spectra of gaseous, liquid, and solid bismuth trichloride. Resonance fluorescence spectra of gaseous BiCl and BiBr

E. Denchik, S. C. Nyburg, G. A. Ozin and J. T. Szymanski, J. Chem. Soc. A, 1971, 3157 DOI: 10.1039/J19710003157

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements