Issue 0, 1971

Some factors influencing the absolute intensity of the carbonyl stretching modes of a series of transition-metal pentacarbonylhalide derivatives

Abstract

Available data on the absolute i.r. intensities of carbonyl stretching vibrations of the series of transition-metal pentacarbonylhalides of general formula XM(CO)5(X = Cl, Br, l; M = Mn, Re) and XM(CO)5(X = Cl, Br, l; M = Cr, W) has been analysed. The present treatment recognises that a local carbonyl bond moment derivative need not necessarily be colinear with the carbonyl bond.

Article information

Article type
Paper

J. Chem. Soc. A, 1971, 3143-3147

Some factors influencing the absolute intensity of the carbonyl stretching modes of a series of transition-metal pentacarbonylhalide derivatives

G. Keeling, S. F. A. Kettle and I. Paul, J. Chem. Soc. A, 1971, 3143 DOI: 10.1039/J19710003143

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