The reactions of the series of complexes M[Mn(CO)5]2(M = Zn, Cd, or Hg) with Group IIB metal halides, Lewis bases, halogens, hydrogen halides, and organic halides have been studied. Several new Lewis-base adducts with nitrogen donor ligands have been isolated and characterised for both M = Zn and Cd. The relatively stable oxygen donor adduct, Cd[Mn(CO)5]2, (diglyme) is also described (diglyme =[MeO·CH2·CH2]2O).
A. T. T. Hsieh and M. J. Mays, J. Chem. Soc. A, 1971, 729 DOI: 10.1039/J19710000729
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...