Issue 23, 1971

Mechanism and inverse primary kinetic isotope effect in the reaction of fluorenylidene with 3-deuteriocyclohexene

Abstract

3-(9′-Fluorenyl)cyclohexene from the reaction of fluorenylidene with cyclohexene is formed by way of the fluorenyl-cyclohexenyl geminate radical pair; for the hydrogen abstraction leading to this radical pair, kH/kD≃ 0·78.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 1512-1513

Mechanism and inverse primary kinetic isotope effect in the reaction of fluorenylidene with 3-deuteriocyclohexene

J. E. Baldwin and A. H. Andrist, J. Chem. Soc. D, 1971, 1512 DOI: 10.1039/C29710001512

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