Brief treatment of fucosterol 24,28-epoxide with BF3 etherate gives desmosterol by a fragmentation reaction, which could be a model reaction for biological dealkylation of the sterol side-chain in insects.
N. Ikekawa, M. Morisaki, H. Ohtaka and Y. Chiyoda, J. Chem. Soc. D, 1971, 1498 DOI: 10.1039/C29710001498
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