Issue 20, 1971

Angular dependence of substituent effects in rigid, bicyclic systems

Abstract

The rates of alkaline hydrolysis of the isomeric ethyl 5,6-epoxybicyclo[2,2,2]octane-2-carboxylates and ethyl bicyclo[2,2,2]octane-2-carboxylate have been measured and the results analysed in terms of the two limiting models for the transmission of nonconjugative substituent effects—the σ-inductive and the field models.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 1312-1313

Angular dependence of substituent effects in rigid, bicyclic systems

C. L. Liotta, W. F. Fisher and C. L. Harris, J. Chem. Soc. D, 1971, 1312 DOI: 10.1039/C29710001312

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