The presence of alkenyl or aryl radicals converts trimethyl phosphite copper(I) iodide into an extremely potent soluble catalyst capable of decomposing diazo-esters cleanly into the corresponding carbenoid species.
B. W. Peace and D. S. Wulfman, J. Chem. Soc. D, 1971, 1179 DOI: 10.1039/C29710001179
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