In the course of the palladium(II) catalysed autoxidation of cyclohexa-1,4-diene a palladium(I) complex, [Pd2(C6H8)(OAc)2·½(HOAc)], is formed as a by-product; the stoicheiometry has been confirmed by analysis and by thermal decomposition, disproportionation and hydrogenation reactions.
J. M. Davidson, J. Chem. Soc. D, 1971, 1019 DOI: 10.1039/C29710001019
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