ααα-Trifluoroacetophenone is the primary product of the light-induced reaction between benzene and trifluoroacetic acid and a novel acid-catalysed photoaddition of this ketone to benzene subsequently occurs; irradiation of acetyl chloride in benzene gives acetophenone.
D. Bryce-Smith, G. B. Cox and A. Gilbert, J. Chem. Soc. D, 1971, 914 DOI: 10.1039/C29710000914
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