Replacement of SCN– with ClO4– in Cu(tn)2(SCN)2(tn = NH2·CH2·CH2·CH2·NH2) is accompanied by a different bonding mode of the thiocyanate ion; the co-ordination polyhedron of the copper(II) ion in bis(1,3-diaminopropane)isothiocyanatocopper(II) is a distorted trigonal bipyramid, the co-ordination sites being occupied by amino and thiocyanate nitrogen atoms.
M. Cannas, G. Carta and G. Marongiu, J. Chem. Soc. D, 1971, 673 DOI: 10.1039/C29710000673
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