The quantum yield for pyridine displacement by aquation from [Ru(NH3)5(py)]2+ on irradiation at the metal-to-ligand charge-transfer band is a function of the solution pH indicating competitive acid-dependent and acid-independent reactions of a short-lived intermediate or excited state.
P. C. Ford, D. A. Chaisson and D. H. Stuermer, J. Chem. Soc. D, 1971, 530 DOI: 10.1039/C29710000530
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