A nucleotide 2,4-dinitrophenyl ester is the major product of reaction of nucleotides with 2,4-dinitro-fluorobenzene in the absence of trialkylamine whereas trialkylamine catalyses the reaction of fluoride ion with the 2,4-dinitrophenyl ester resulting in the formation of nucleoside phosphorofluoridate.
P. W. Johnson and M. Smith, J. Chem. Soc. D, 1971, 379 DOI: 10.1039/C29710000379
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